Aside from the sides that were eliminated unbeaten in the group a stages, there aren't that many sides that have exited the World Cup unbeaten -- if you disregard a loss in a penalty shoot-out as a defeat. I count ten (or twelve) since the first penalty shootout in the World Cup in 1982.
Of course, if there is a penalty shoot-out in the semis, we might be able to add to this list
2014: Costa Rica (P5 W2 D3 L0)
2006: Argentina (P5 W3 D2 L0)
2006: England (P5 W3 D2 L0)
2006: Switzerland (P4 W2 D2 L0)
2002: Spain (P5 W3 D2 L0)
2002: Ireland (P4 W1 D3 L0)
1998: Italy (P5 W3 D2 L0)
1990: Italy (P7 W6 D1 L0)
1986: Brazil (P5 W4 D1 L0)
1986: Mexico (P5 W3 D2 L0)
Netherlands were undefeated in 1998 when the were beaten by Brazil in the semi on penalties, but they lost their third-place play-off to Croatia.
England in 1990 lost to Germany on penalties in the semis and to Italy in the third-place play-off. After 90 minutes, England won one, lost one, and drew FIVE!
Of course, if there is a penalty shoot-out in the semis, we might be able to add to this list
2014: Costa Rica (P5 W2 D3 L0)
2006: Argentina (P5 W3 D2 L0)
2006: England (P5 W3 D2 L0)
2006: Switzerland (P4 W2 D2 L0)
2002: Spain (P5 W3 D2 L0)
2002: Ireland (P4 W1 D3 L0)
1998: Italy (P5 W3 D2 L0)
1990: Italy (P7 W6 D1 L0)
1986: Brazil (P5 W4 D1 L0)
1986: Mexico (P5 W3 D2 L0)
Netherlands were undefeated in 1998 when the were beaten by Brazil in the semi on penalties, but they lost their third-place play-off to Croatia.
England in 1990 lost to Germany on penalties in the semis and to Italy in the third-place play-off. After 90 minutes, England won one, lost one, and drew FIVE!
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