Barbara Stanwyck in Double Indemnity, Marilyn Monroe in Some Like it Hot, or Sue Lyon in Lolita.
Overall though my vote goes to Harry Lime too. In fact Orson Welles made quite a few classic entrances: the giant lips in Citizen Kane and the low shot as he emerges from the car in Touch of Evil too
Walter Matthau as the shyster lawyer in Billy Wilder's The Fortune Cookie. The very first shot of him is from behind as the smoke of his cigar curls up around him, while a sneaky Andre Previn underscore nails him from the start. Before you see his face, you know what he'll be up to.
I luuuurve Barbara Stanwyck. Straight or comedy she does the best deadpan ever, says more with her eyes in thirty seconds than most actors can in an entire movie. I watched Baby Face twice last weekend — the original uncensored version. Stanwyck plays a character who unabashedly fucks her way to wealth in mid- 30s Manhattan after being turned on to Nietzsche. Couldn't take my eyes off her.
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